When a gas expands, it does work and its internal energy decreases. Since added heat increases the internal energy of a system, Q is positive when it is added to the system and negative when it is removed from the system. The first law states that the change in internal energy of that system is given by Q-W. Suppose Q represents the heat exchanged between a system and the environment, and W is the work done by or on the system. We will see in this chapter how internal energy, heat, and work all play a role in the first law of thermodynamics. His humorous statement of the first law of thermodynamics is stated “you can’t win,” or in other words, you cannot get more energy out of a system than you put into it. Snow (1905–1980) is credited with a joke about the four laws of thermodynamics. This interaction is given by the first law of thermodynamics. Now that we have seen how to calculate internal energy, heat, and work done for a thermodynamic system undergoing change during some process, we can see how these quantities interact to affect the amount of change that can occur.
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